While Roberto and Mauro investigate the case of an artist who disfigured two young people with a solvent used in painting, Giulia interrogates Lieutenant Riva, suspected of complicity in covering up the disappearance of Captain Rea. The carabiniere firmly denies his involvement and the commissioner decides to have Luca and Anna follow him. Roberto and Mauro will be able to reconstruct the delirious plan for revenge of Rinaldi, the painter whose wife lost an eye due to a beer can thrown from an overpass while their car was in transit. With Giulia's help, they will save Daria, the last girl suspected of the act by Rinaldi, who will be arrested. Meanwhile, Luca and Anna continue their search for Captain Rea.